Electron microscopy study of domain structure due to phase transitions in natural perovskite     

Yanbin Wang  Robert C. Liebermann 《Physics and Chemistry of Minerals》1993,20(3):147-158

Transmission electron microscopy on natural calcium metatitanate perovskite (dysanalyte) reveals the following twin laws in the orthorhombic (space group Pbnm) phase: reflection twins on the {110} and {112} planes, and 90° rotation twins about the [001] axis (referred to as [001]_90° twin). Single crystals that were heattreated and quenched from above 1585 K exhibit a dramatic change in domain structure compared with the starting material and specimens quenched from T < 1470=" k.=" mutually=" perpendicular=" {110}=" and=">_90° twins are observed throughout the crystal, forming a cross-hatched domain texture. 1/2[001] antiphase domains, which are very rarely observed in the starting material, also become dominant in the crystal. This change in domain structure is interpreted as due to a structural phase transition in perovskite at a temperature below 1585 K. From the point symmetry elements that describe the twin laws and the translational elements that relate the antiphase domains, the most likely phase near 1585 K is tetragonal with space group P4/mbm. These results are consistent with high-temperature powder X-ray diffraction study. On the other hand, density of the {112} twins is increased significantly in the crystal quenched from 1673 K. Twin domains are either bound by mutually perpendicular {110} and (001) walls, or by {112} walls with {110} twin domains within the polygonal {112} domains. Both twin density variation and domain morphology suggest that the crystal may be cubic at this temperature. Microstructure of a single crystal deformed at 1273 K and 3.5 GPa (within the orthorhombic stability field) is morphologically quite distinct from that of the heat-treated specimens. Dislocations dominate the microstructure and often interact with twin domain boundaries.A National Science Foundation Science and Technology Center  相似文献   

The ‘ultimate objective’ of the framework convention on climate change requires a new approach in climate change research     

Robert J. Swart  Pier Vellinga 《Climatic change》1994,26(4):343-349

In the Framework Convention on Climate Change an ultimate objective is formulated that calls for stabilization of the concentrations of greenhouse gases in the atmosphere at a level that would allow ecosystems to adapt naturally, safeguard food supply and enable sustainable development to proceed in a sustainable manner. This paper addresses the possible contribution of science to translate this rather vague and ambiguous objective into more practicable terms. We propose a regionalized, risk-based six-step approach that couples an analysis of ecosystem vulnerability to the results of simulations of climate change. An ultimate objective level could be determined in terms of stabilized concentrations of greenhouse gases in the atmosphere. The level and timing of this stabilization would be determined by a political appreciation of associated risks for managed and unmanaged ecosystems. These risks would be assessed by region in an internationally coordinated scientific effort, followed by a global synthesis.  相似文献   

Solar and stellar chromospheric contrast     

Robert A. Donahue  Sergio R. Restaino  Stephen L. Keil 《Solar physics》1994,149(2):257-265

Positions of active regions estimated from observations of the whole solar disk in Caii K _iv during the period 1977–1989 at the Coimbra Astronomical Observatory are compared with the time-dependent latitudinal distribution of background solar magnetic fields and with the latitudinal shifts of boundaries of their polarities. We confirm that the sunspot groups are located near the zonal boundaries between the opposite polarities of the solar background magnetic field during different phases of the two recent consecutive cycles of activity. We demonstrate a probable connection between the increased number of groups and the commencement of poleward migration of zonal boundaries in both hemispheres. But the influence of the dominant convective rolls seems to he still unclear. A new problem of interrelation between the zonal and sector boundaries has also appeared.  相似文献   

Magmatism in the eastern Aleutian Arc: temporal characteristic of igneous activity on Akutan Island   总被引：1，自引：0，他引：1  

Jay D. Romick  Michael R. Perfit  Samuel E. Swanson  Robert D. Shuster 《Contributions to Mineralogy and Petrology》1990,104(6):700-721

Lavas from Akutan Island, located in the eastern Aleutian arc at the transition between continental and oceanic crust, show a gradual change in their petrologic and chemical characteristics over the last 4 million years. The oldest lavas exposed on the island, the Hot Springs Bay Volcanics (HSBV), range from magnesian basalt to dacite (45%–62% SiO₂). The most mafic basalts contain salitic clinopyroxene, Cr- and Al-rich spinel, and pargasitic amphibole suggesting that they were derived from relatively hydrous magmas at greater pressures than lavas from the younger Akutan Volcanics (AKV) and the modern volcano (MOD). AKV lavas also range between basalt and dacite (46%–63% SiO₂), but contain no hydrous phenocrysts and seem to have fractionated within a shallow level magma chamber. Lavas from the modern volcano are andesitic (52%–57% SiO₂) and have a mineral assemblage similar to that of AKV lavas of similar composition. With the exception of clinopyroxene and spinel in the most mafic lavas, the compositions of plagioclase (An_92?45), olivine (Fo_88?51), orthopyroxene (En_69?56), and titanomagnetite (15%–21% TiO₂) phenocrysts found in these lavas are within the range observed in lavas from other Aleutian volcanoes. Variations in the major element chemistry of the older lavas can be reproduced by fractional crystallization of the observed mineral assemblages, however closed system crystal fractionation models are inadequate to explain the trace element variations. During the last 4 million years, La/Yb ratios have decreased (6.5–3.3 for HSBV lavas and 2.9–1.9 for MOD lavas) whereas Ba/La ratios appear to have increased slightly (37–43 for HSBV and AKV, and 41–45 of MOD). The lower La/Yb ratios of MOD lavas correspond with lower total abundances of the REE and slightly higher Sr and Pb isotopic ratios. The increased⁸⁷Sr/⁸⁶Sr ratios and Pb isotopic ratios in the MOD lavas, the less enriched LREE, and the higher Ba/La ratios may result from partial melting of an arc source which has experienced previous melting events but has continued to be contaminated by a component from the subducting slab. It may also indicate a change in the degree of partial melting of the underlying mantle, which corresponds to a different percentage of a slab derived component being incorporated into the overlying mantle.  相似文献   

Sm−Nd and Pb isotopic study of mafic rocks associated with early Proterozoic continental rifting: the Peröpohja schist belt in northern Finland     

Hannu Huhma  Robert A. Cliff  Vesa Perttunen  Matti Sakko 《Contributions to Mineralogy and Petrology》1990,104(3):369-379

The Peräpohja schist belt in northern Finland rests unconformably on Archaean granitoids, and marks the early stages of Proterozoic crustal evolution in the Fennoscandian (Baltic) shield. 2440 Ma old layered mafic intrusions predate the supracrustal , and ca. 2200 Ma old sills of the gabbro-wehrlite association intrude the lowest quartzites and volcanics (Runkaus) of the sequence. The Sm-Nd mineral isochron of the Penikat layered intrusion gives an age of 2410±64 Ma. The initial _Nd-values of the Penikat intrusion (_Nd(2440) = –1.6) and the Runkausvaara sill (_Nd(2200) 0) suggest that these mafic magmas were contaminated by older crustal material. The Sm-Nd and Pb isotopic results on the 2.44–2.2 Ga old Runkaus volcanics indicate mobility of Pb, fractionation of Sm/Nd during late greenschist facies metamorphism, and crustal contamination. The Pb-Pb data provide an age of 1972±80 Ma with a high initial ²⁰⁷Pb/²⁰⁴Pb ratio (₁ = 8.49), while scattered Sm-Nd data result in an imprecise age of 2330±180 Ma, with an initial _Nd-value of about zero. Secondary titanite gives an U-Pb age of ca. 2250 Ma. The Jouttiaapa basalts, in contrast, ascended from the mantle without interaction with older crust. These LREE depleted tholeiites mark a break in continental sedimentation, and yield a Sm-Nd age of 2090±70 Ma. Their initial _Nd = + 4.2 ±0.5 implies that the subcontinental early Proterozoic mantle had been depleted in LREE for a long period of time. The first lava flows are strongly depleted in LREE, suggesting that their source was significantly more depleted than the source of mid-ocean ridge basalts today.  相似文献   

Recent crustal subsidence at Yellowstone Caldera,Wyoming     

Daniel Dzurisin  James C Savage  Robert O Fournier 《Bulletin of Volcanology》1990,52(4):247-270

Following a period of net uplift at an average rate of 15±1 mm/year from 1923 to 1984, the east-central floor of Yellowstone Caldera stopped rising during 1984–1985 and then subsided 25±7 mm during 1985–1986 and an additional 35±7 mm during 1986–1987. The average horizontal strain rates in the northeast part of the caldera for the period from 1984 to 1987 were: ₁ = 0.10 ± 0.09 strain/year oriented N33° E±9° and ₂ = 0.20 ± 0.09 strain/year oriented N57° W±9° (extension reckoned positive). A best-fit elastic model of the 1985–1987 vertical and horizontal displacements in the eastern part of the caldera suggests deflation of a horizontal tabular body located 10±5 km beneath Le Hardys Rapids, i.e., within a deep hydrothermal system or within an underlying body of partly molten rhyolite. Two end-member models each explain most aspects of historical unrest at Yellowstone, including the recent reversal from uplift to subsidence. Both involve crystallization of an amount of rhyolitic magma that is compatible with the thermal energy requirements of Yellowstone's vigorous hydrothermal system. In the first model, injection of basalt near the base of the rhyolitic system is the primary cause of uplift. Higher in the magmatic system, rhyolite crystallizes and releases all of its magmatic volatiles into the shallow hydrothermal system. Uplift stops and subsidence starts whenever the supply rate of basalt is less than the subsidence rate produced by crystallization of rhyolite and associated fluid loss. In the second model, uplift is caused primarily by pressurization of the deep hydrothermal system by magmatic gas and brine that are released during crystallization of rhyolite and them trapped at lithostatic pressure beneath an impermeable self-sealed zone. Subsidence occurs during episodic hydrofracturing and injection of pore fluid from the deep lithostatic-pressure zone into a shallow hydrostatic-pressure zone. Heat input from basaltic intrusions is required to maintain Yellowstone's silicic magmatic system and shallow hydrothermal system over time scales longer than about 10⁵ years, but for the historical time period crystallization of rhyolite can account for most aspects of unrest at Yellowstone, including seismicity, uplift, subsidence, and hydrothermal activity.  相似文献   

Sensitivity of glaciation to initial snow cover,CO2, snow albedo,and oceanic roughness in the NCAR CCM     

Robert J Oglesby 《Climate Dynamics》1990,4(4):219-235

We present results from numerical experiments made with a GCM, the NCAR CCM1, that were designed to estimate the annual balance between snow-fall accumulation and ablation for geographically important land regions for a variety of conditions. We also attempt to assess the reliability of these results by investigating model sensitivity to changes in prescribed physical parameters. Experiments were run with an initial imposition of 1 m of (midwinter) snowcover over all northern hemisphere land points. Over Alaska, western Canada, Siberia, and the Tibetan Plateau the model tended to retain this snow cover through the summer and in some cases increase its depth as well. We define these regions as glaciation sensitive and note some correspondence between them and source regions for the Pleistocene ice sheets. An experiment with greatly reduced CO₂ (100 ppm) showed a tendency towards spontaneous glaciation, i.e., the model remained snow-covered throughout the summer over the same geographic regions noted above. With 200 ppm CO₂ (roughly equal to values at the last glacial maximum), snow cover over these regions did not quite survive the summer on a consistent basis. Combining 200 ppm CO₂ and 1 m of initial northern hemisphere snow cover yielded glaciation-sensitive conditions, agreeing remarkably well with locations undergoing glaciation during the Pleistocene. To assess the reliability of these results, we have determined minimal model uncertainty by varying two of the empirical coefficients in the model within physically plausible ranges. In one case surface roughness of all ocean gridpoints was reduced by an order of magnitude, leading to local 10% reductions in precipitation (snowfall), a change hard to distinguish from inherent model variability. In the other case, the fraction of a land grid square assumed to be occupied by snow cover for albedo purposes was varied from one-half to unity. Large changes occurred in the degree of summer melting, and in some cases the sign of the net balance changed as fractional snow cover was changed. We conclude that the model may be able to reveal regions sensitive to glaciation, but that it cannot yield a reliable quantitative computation of the magnitude of the net snow accumulation that can be implicitly or explicitly integrated through time.This paper was presented at the International Conference on Modelling of Global Climate Change and Variability, held in Hamburg 11–15 September 1989 under the auspices of the Meteorological Institute of the University of Hamburg and the Max Planck Institute for Meteorology. Guest Editor for these papers is Dr. L. Dilmenil  相似文献   

Natural recolonization of a productive tropical pond: Day to day variations in the photosynthetic parameters     

Robert Arfi  Daniel Guiral  Jean-Pascal Torreton 《Aquatic Sciences - Research Across Boundaries》1991,53(1):39-54

Chlorophyll pigments (CHL), primary productivity (PP) and particulate nitrogen (N_p) in relation to several environmental factors were monitored during planktonic colonization of an aquaculture pond (Layo, Côte d'Ivoire). How interactions between the organisms are established in an initially azoic environment were investigated. From March, 15 (D1) to March, 31 (D16), the system transformation went through three stages. First, a precolonization by heterotrophic microbial community from D1 to D2 (N_p < 1 m maximum at D2: 243 mg m^–2; CHL around 0). Then, a pioneer microalgal community developped from D3 to D7 (maximum CHL on D6: 19 mg m^–2; PP: 1.0 g C m^–2 d^–1) with a significant contribution of picoplankton (CHL and PP < 3 m: 33 and 23% of the total, respectively). Finally, a second microalgal colonization was noticed from D9 to D12 (maximum CHL: 55 mg m^–2, PP: 2.8 g C m^–2 d^–1), largely dominated by nanoplankton (CHL and PP > 3 m: 95 and 99% of the total, respectively). Overall, photosynthetic activity appeared to be closely linked to algal biomass. The study of autotrophic biomass and activity in different size classes in relation to the other parameters allowed us to precise the origin of the biomass fluctuations. The first bloom appeared to be controlled by selective grazing on small algae. The second algal development ended when N requirement represented at least 69% of N supply (in the N — NH₄ form). This control was enhanced by the appearance of rotifers, leading to a more complex equilibrium.  相似文献   

V792 Her=HD 155638: A totally eclipsing RS CVn binary     

Charles H. Nelson  Douglas S. Hall  Francis C. Fekel  Robert E. Fried  Richard E. Lines  Helen C. Lines 《Astrophysics and Space Science》1991,182(1):1-17

Photometry of HD 155638=V792 Her has been analyzed to determine the elements of this totally eclipsing RS CVn binary. The light variation outside eclipse was found to have a period of 27^d.07±0^d.07, which is slightly different from the 27^d.5384±0^d.0045 orbital period. Analysis of the eclipses was achieved by a modification of the Russell-Merrill technique. With the aid of radial velocity measures, absolute elements were obtained for the hot and cool stars, respectively;R _h=2.58R ,R _c=12.28R ,M _h=1.40M ,M _c=1.46M ,i=80^o.61 and velocity semi-amplitudesK _c=48.36 km s^–1±0.79 km s^–1, andK _h=50.50 km s^–1±0.33 km s^–1. The apparent magnitudes areV _h=9 ^m .73 andV _c=8 ^m .48. The distance to HD 155638 was estimated to be 310 parsecs.  相似文献   

Sunspot group areas and the latitude distance from the average latitude of activity     

Robert F. Howard 《Solar physics》1991,135(2):339-342

Digitized Mount Wilson sunspot data from 1917 to 1985 are analyzed to examine group areas as a function of latitude distance () from the central latitude of activity in each hemisphere. On average these group areas are larger for the smallest values of ¦¦. The effect is similar to that seen for the magnetic fields of active regions (Howard, 1991). It is concluded that this is fundamentally a dependence, and not a latitude dependence. The suggestion is made that the cause of this effect is the influence of large-scale convective motions on the rising flux tubes that make up the active regions. The smaller flux tubes (spot groups) are more easily displaced in latitude during their ascent to the surface by this velocity field than are the larger flux tubes.Operated by the Association of Universities for Research in Astronomy, Inc., under Cooperative Agreement with the National Science Foundation.  相似文献